01
Adding from weekday onto the holy
The Gemara in Yoma (פ״א ע״ב (81b)) learns from "you shall rest your rest" that one adds from weekday onto the holy - at entry and exit. The poskim dispute whether this is Torah-level or rabbinic.
בין השמשות
The time between sunset and nightfall - possibly day, possibly night; stringencies of both days apply.